Chemguide: Support for CIE A level Chemistry
Learning outcome 13
13.4: Isomerism: structural and stereoisomerism
This statement expects you to be able to draw all the possible isomers of a compound if you are told its molecular formula.
In truth, the only way of preparing for this is to do as many questions as you can find. The problem is that if it comes up in a multiple choice paper, all they can really ask for is a total number of isomers. Although you can find that out from the mark scheme, it doesn't help you to identify the ones you have missed, or the extra ones that are wrong.
This statement is new in the 2022 syllabus, and I can only hope that the questions they ask are simple, involving small numbers of atoms.
Try to do it systematically.
This will become easier when you have done a lot more chemistry, because you will get to know the likely possibilities.
So, for example, if you were given a molecular formula like C4H8O2, you would immediately recognise that compounds with two oxygens in are most likely to be carboxylic acids or esters, and so you would find as many of those as you could.
But there are also others isomers that you would need to think of as well. There could be a C=O group somewhere and an OH group somewhere else on the chain. Or there could be two OH groups and a carbon-carbon double bond, in which case you might have geometric isomers as well.
To be honest, this is a nightmare statement!
© Jim Clark 2020